Trace Elements in West Virginia Coals
Ash Yield Distribution in West Virginia Coals
Ash Yield stratigraphic distribution in West Virginia coals shows low ash in coals of the Pocahontas through lower Kanawha Formations, then a gradual increase in average ash yields in coals from the upper Kanawha Formation through the Dunkard Group, with lower ash yield in coals of the Monongahela Group. Statistical correlations between ash yield and trace elements revealed that chromium (Cr) correlated well and other elements correlated moderately. Elements that correlated with ash yield were generally associated with clays and monazite. Rare earth elements (REE), despite their association with the detrital mineral monazite, correlated poorly with ash yield.
| Element | Cr | Th | Sc | Cs | Rb | Li | V | Hf | Ce | La |
|---|---|---|---|---|---|---|---|---|---|---|
| r | +0.8348 | +0.7912 | +0.7691 | +0.7623 | +0.7473 | +0.7393 | +0.7304 | +0.7058 | +0.6875 | +0.6738 |
| # samples | n = 844 | n = 822 | n = 845 | n = 781 | n = 403 | n = 845 | n = 844 | n = 509 | n = 546 | n = 545 |
| Mineral association | clays and chromite | monazite | clays and phosphates | clays | clays | clays | clays | zircon | monazite | monazite |
| Group | REE | REE |
| Element | Zr | Ta | Nb | Dy | Ho | Pb | Sm | Eu | Ga | Te |
|---|---|---|---|---|---|---|---|---|---|---|
| r | +0.6705 | +0.6576 | +0.6541 | +0.6462 | +0.6451 | +0.6440 | +0.6349 | +0.6177 | +0.6159 | +0.6078 |
| # samples | n = 747 | n = 462 | n = 832 | n = 78 | n = 48 | n = 842 | n = 538 | n = 540 | n = 844 | n = 113 |
| Mineral association | zircon | zircon | rutile? | monazite | monazite | galena & clausthalite | monazite | monazite | clays & sulfides | |
| Group | REE | REE | REE | REE |
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Page content last revised: March 1, 2002
