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Trace Elements in West Virginia Coals

Ash Yield Distribution in West Virginia Coals

Chart of average ash yield, in percent on a dry whole coal basis, for each West Virginia coal bed in stratigraphic order (larger version)
Select the chart to open a larger version.

Ash Yield stratigraphic distribution in West Virginia coals shows low ash in coals of the Pocahontas through lower Kanawha Formations, then a gradual increase in average ash yields in coals from the upper Kanawha Formation through the Dunkard Group, with lower ash yield in coals of the Monongahela Group.  Statistical correlations between ash yield and trace elements revealed that chromium (Cr) correlated well and other elements correlated moderately.  Elements that correlated with ash yield were generally associated with clays and monazite. Rare earth elements (REE), despite their association with the detrital mineral monazite, correlated poorly with ash yield.

Spearman Correlation Coefficients (r) with Ash Yield
Element Cr Th Sc Cs Rb Li V Hf Ce La
r +0.8348 +0.7912 +0.7691 +0.7623 +0.7473 +0.7393 +0.7304 +0.7058 +0.6875 +0.6738
# samples n = 844 n = 822 n = 845 n = 781 n = 403 n = 845 n = 844 n = 509 n = 546 n = 545
Mineral association clays and chromite monazite clays and phosphates clays clays clays clays zircon monazite monazite
Group  REE  REE
Element Zr Ta Nb Dy Ho Pb Sm Eu Ga Te
r +0.6705 +0.6576 +0.6541 +0.6462 +0.6451 +0.6440 +0.6349 +0.6177 +0.6159 +0.6078
# samples n = 747 n = 462 n = 832 n = 78 n = 48 n = 842 n = 538 n = 540 n = 844 n = 113
Mineral association zircon zircon rutile? monazite monazite galena & clausthalite monazite monazite clays & sulfides
Group REE REE REE REE

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Page content last revised: March 1, 2002